Sublithospheric diamonds and the inclusions they may carry crystallize in Earth's asthenosphere, mantle transition zone, or uppermost lower mantle (from 300 to ~800 km). They are the deepest minerals so far recognized to form by plate tectonics. These diamonds are distinctive in their deformation features, low nitrogen content, and inclusions of high pressure mantle minerals such as majorite, ringwoodite, perovskite, ferropericlase, and bridgmanite or their equivalent compositions transformed to lower-pressure minerals. The isotopic composition of boron, carbon, and nitrogen in the diamonds and/or oxygen, iron and magnesium in inclusions are typically well outside normal mantle compositional ranges. These differences from normal mantle indicate that the diamond-forming fluids were modified by interaction with seawater in so-called oceanic slabs before the slabs were subducted.
Metamorphic minerals formed in oceanic slabs, especially when they are cold, are effective hosts that transport carbon as carbonate and hydrogen as water, hydroxyl, or methane below the mantle wedge of the island arc–mantle system. Warming of the slab generates carbonatitic melts, supercritical aqueous fluids, or metallic liquids from these minerals, forming three basic types of sublithospheric diamonds. Diamond crystallization occurs by movement and reduction of these mobile fluids as they pass through host mantle via fractures —a process that creates chemical heterogeneity in the mantle and may promote deep focus earthquakes. The geobarometry of majorite and diamond ages suggest mobility of mantle carrying the diamonds upwards, perhaps to the base of mantle lithosphere as part of the supercontinent cycle. From there, diamonds are finally transported to Earth’s surface by eruptions of kimberlite magma.
Mineral assemblages in sublithospheric diamonds directly trace a deep volatile cycle, demonstrating how the hydrosphere of a rocky planet such as Earth can connect to its solid interior.
Shirey, S.B., Pearson, D.G., Stachel, T., Walter, M.J. (2024) Sublithospheric Diamonds: Plate Tectonics from Earth's Deepest Mantle Samples, Annual Review of Earth and Planetary Sciences 52, 9.1-9.45